NeoNickel

UNS S31803/2205

A cost-effective duplex stainless steel, UNS S31803/2205 combines high strength with excellent resistance to pitting, crevice corrosion and chloride stress-corrosion cracking in aggressive environments. Available from NeoNickel in sheet, plate, round bar, pipe and tube.

Characteristics of UNS S31803/2205

UNS S31803/2205 (also known as duplex 2205 or 1.4462) is a 22% chromium duplex stainless steel with a balanced ferritic-austenitic microstructure containing roughly 40 to 50% ferrite in the annealed condition. The combination of chromium, molybdenum and nitrogen delivers the high strength of ferritic grades alongside the corrosion resistance of austenitic grades, typically at a lower cost than high-nickel austenitic alternatives.

The grade is widely specified for warm seawater, sour-gas and chloride-rich service in the oil and gas, chemical processing and pulp and paper industries where 316L and 317L stainless steels are no longer adequate.

Key Benefits of Alloy UNS S31803/2205:

  • Yield strength roughly twice that of standard austenitic stainless steels
  • Excellent resistance to chloride pitting and crevice corrosion (PREN ≥ 35)
  • High resistance to chloride stress-corrosion cracking
  • Resistance to sulphide stress-corrosion cracking in sour-gas environments
  • Good general corrosion resistance in seawater and most sulphuric acid concentrations
  • Cost-effective alternative to high-nickel austenitic grades such as 904L
  • UNS Number: S31803/S32205
  • Werkstoff Number: 1.4462
  • ASTM: A182 (F51), A240, A276, A479, A789, A790, A815
  • AMS:
  • Other: ASME: SA182, SA240, SA479, SA789

Product availability

We stock UNS S31803/2205 in a range of product forms to suit different applications and fabrication methods, including sheet, plate, round bar, pipe and tube. To view available sizes and submit an enquiry, use the dropdown selector below.

Plate
Sheet

Chemical analysis

The following elements give UNS S31803/2205 its balance of high strength and resistance to pitting, crevice corrosion and stress-corrosion cracking.

%CrFeMoNNiPSSi
Min22Balance30.144.50--0.20
Max23-3.500.205.500.0300.0200.70

Key Properties

  • Density : 7.805 g/cm³
  • Melting Range: 1385-1441 ⁰C
  • Hardness, Vickers: 310
  • PREN : ≥ 35
  • Microstructure : 40 to 50% ferrite in the annealed condition
  • Maximum service temperature : around 300°C (higher temperatures risk 475°C embrittlement and sigma-phase formation)

UNS S31803/2205 is built for long service in chloride-bearing, sour-gas and sulphuric acid environments. Key physical and mechanical properties include:

About UNS S31803/2205

UNS S31803/2205 is a 22% chromium duplex stainless steel developed to combine the strength of ferritic grades with the corrosion resistance of austenitic grades. It is dual-certified to both UNS S31803 and the tighter-chemistry UNS S32205, and meets Werkstoff 1.4462 under EN standards. Most modern material is produced to meet both UNS numbers simultaneously.

The difference between UNS S31803 and UNS S32205 comes down to tightened chemistry ranges in S32205:

  • Chromium: 22.0 to 23.0% (S32205) versus 21.0 to 23.0% (S31803)
  • Molybdenum: 3.0 to 3.5% (S32205) versus 2.5 to 3.5% (S31803)
  • Nitrogen: 0.14 to 0.20% (S32205) versus 0.08 to 0.20% (S31803)
  • Nickel: 4.5 to 6.5% for both, typically running higher in S32205

The S32205 range guarantees better pitting resistance and as-welded corrosion performance, which is why many modern specifications call for dual S31803/S32205 certification.

Three alloying elements work together to deliver this performance:

  • Chromium: delivers oxide film stability and general corrosion resistance
  • Molybdenum: sharply improves pitting and crevice corrosion resistance in chloride environments
  • Nitrogen: stabilises the austenite phase, raises yield strength and improves as-welded pitting resistance

Welding and fabrication

UNS S31803/2205 can be welded using standard stainless steel processes including GTAW, GMAW, SMAW and SAW. Recommended filler metals and procedures:

  • Standard filler: AWS ER2209 bare wire or E2209 covered electrodes, with higher nickel than the base metal for correct weld phase balance
  • Dissimilar metal welds: a filler with sufficient austenite-forming elements to avoid fully ferritic weld zones
  • Preheat: not normally required
  • Post-weld heat treatment: not usually needed if welding procedures are followed correctly
  • Solution anneal (if required): 1040°C followed by rapid water quenching

NeoNickel supplies UNS S31803/2205 in sheet, plate, round bar, pipe and tube, all with full mill certification and traceability, supported by technical guidance from our specialist team.

Applications of UNS S31803/2205

With its high strength and resistance to chloride-induced pitting, crevice corrosion and stress-corrosion cracking, UNS S31803/2205 is specified across industries where austenitic stainless steels fall short. Duplex stainless steel UNS S31803 plate is commonly used for pressure vessels and tank fabrication, while duplex UNS S31803 pipe and tube are widely specified for corrosive fluid handling.

Oil, Gas & Marine

  • Seawater systems, pumps and valves
  • Offshore piping and risers
  • Oil field tubing and production piping
  • Subsea manifolds and fittings

Chemical Processing

  • Chemical process vessels and reactors
  • Heat exchangers and condensers
  • Piping and fittings in sulphuric acid service
  • Storage tanks for aggressive media

Pulp, Paper & Environmental

  • Pulp mill digesters and bleach washers
  • Liquor storage tanks
  • Flue-gas desulphurisation (FGD) scrubber systems
  • Waste-water treatment equipment

Food & Industrial

  • Food processing equipment and tanks
  • Brewery and distillery vessels
  • Structural components in bridges and coastal infrastructure

This combination of properties makes UNS S31803/2205 a common choice across industries that demand both strength and corrosion resistance.

  • Seawater systems
  • Seawater pumps and valves
  • Chemical process vessels, piping, and heat exchangers
  • FGD scrubber systems
  • Pulp mill digesters, bleach washers
  • Food process equipment
  • Oil field piping

Frequently Asked Questions

What is UNS S31803/2205?
What is the difference between UNS S31803 and UNS S32205?
What is 2205 duplex stainless steel used for?
Is UNS S31803/2205 corrosion resistant?
What is the temperature limit of duplex UNS S31803/2205?
Can UNS S31803/2205 be welded?
What forms of UNS S31803/2205 does NeoNickel supply?

Why Choose NeoNickel for UNS S31803/2205?

NeoNickel supplies UNS S31803/2205 across the UK and Europe, supporting both urgent requirements and long-term project needs. All material is supplied with NACE MR0175 and NORSOK MDS D45 certification where required for sour service, alongside full mill traceability to ASTM and ASME standards. Our technical team can help specify the right form for oil and gas, chemical processing and marine applications.

If you're unsure which grade or form is right for your application, fill out our enquiry form and a member of the team will be in touch.

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